It would be nice if there were multiple reviews available. If you're looking for an expert guide to every nut and bolt of the Entity Framework (EF) - I'm not sure this is the book.
If you're looking for a quickstart, I think this is a decent book. But, anybody can draw a model without a book. The challenge is DOING something with that model, and that takes a little more than a 1 page MSDN tutorial.
The challenge is that if you're going to talk about EF, there are hundreds of semi-directly related topics. LINQ, Entity Queries, WCF, WPF, Silverlight, MVC. There is no way any book could cover everything you can do with EF.
However, this book covers all the core topics very well. As someone relatively new to LINQ, WCF, and MVC, it was great. As someone who is familiar with databinding, but never really used it (because it's been mostly awful), it was nice to get into it.
So, 5 stars might be a little high, but this book did everything I wanted:
1. It gave enough detail to help me start reasonably quick.
2. It covered all the related technologies with enough depth that I don't have to buy a LINQ book, WPF book, etc, just to use EF.
So, if you're newer to the 2010 technologies, I think this is a great place to start.