It's almost impossible to find a laboratory textbook in electrochemistry written after 1920, and since then so many things have changed you might need an emeritus chemist to traslate it for you (that's why I start by giving this book PLUS TWO STARS).
Also, for general chemistry electrochemical experiments are pretty easy to find, but that's not the case with other basic courses like organic, inorganic and physical chemistry.
In the case of physical chemistry Shoemaker (Experiments in Physical Chemistry), Matthews (Experimental Physical Chemistry) and Athawale (Experimental Physical Chemistry) include some classical nice experiments, but they're just not enough and most of them emphasize the basic science aspects alone.
In this book Holze manages to squeeze laboratory experiments for elementary, basic and intermediate (PLUS ONE STAR) electrochemistry, electroanalysis and electrosynthesis (PLUS TWO STARS) and in some of them also includes the applied science aspect of the experiment like corrosion and batteries (PLUS ONE STAR). You should really take a look at the table of contents.
The MINUS ONE STAR comes from the book's lack of equipment diagrams and detailed instructions. It's more a guide for the instructors than a real laboratory textbook. Also, the book leaves behind all the possibilities of amalgam electrodes (and yes, the environmental issue can be a problem if your ignorance ocludes you from keeping them in good conditions) and some other do-it-yourself systems (MINUS ONE STAR).
NOTE: You will probably need to complement this book with Sawyer's (Electrochemistry for Chemists), and in the case you're interested in amalgams you can look in any old preparative inorganic chemistry book like Brauer's (Handbook of Preparative Inorganic Chemistry, Volume 1 and 2, Complete 2 Volume Set).