I am a BIG fan of the Adobe Classroom in a Book (CIB) series. I constantly recommend the books to folks who want to get up to speed on Adobe's software. So ... I come to this review slightly prejudiced. Just wanted to get that out of the way up front.
The thing I like best about Adobe's CIB series is that it is truly a tutorial, not just a reference book. (Though you can use it as a reference quite easily.)
If you will take a little time and do the lessons in the book in order, you'll learn all the basic (and some beyond) skills that you need. The included CD-ROM contains all the files you need to do the tutorials.
I'm working through the GoLive 6 CIB myself. I've used GoLive since a pretty early edition, but it seems that Adobe changes the workings of GoLive considerably with each new edition and I have been neglecting my web sites for quite some time, so I've forgotten how some things work. Adobe GoLive 6.0 Classroom in a Book is exactly what I needed.
There is a very logical, step-by-step progression to its organization. It covers the basics, and some very advanced features. From basic web page design, to floating boxes, animations, rollovers, cascading style sheets (one of my weak areas), drop down menus, javascript, and site management, it covers it thoroughly.
If you are trying to learn GoLive in order to build yourself some web presence, this book will be a GREAT help. Just work through the tutorials, and you'll learn it. (It certainly beats paying hundreds or thousands of dollars for training.)